Self-assembling 1D core/shell microrods by the introduction of additives: a one-pot and shell-tunable method.
نویسندگان
چکیده
Herein, we have developed a one-pot method for the fabrication of one-dimensional core/shell microrods with tunable shell compositions by the introduction of additives. Crystalline dimethyl melamine hydrochloride was utilized as the core, while melamine derivatives with different functional groups, such as pyrene, thiophene and naphthalene diimide, served as additives to regulate the core morphology and were adsorbed as the shell. The length and width of these one-dimensional structures can be tuned by varying the molar ratio of core and shell molecules as well as their total concentration. Through X-ray diffraction, the detailed molecular arrangements within the core of the microrods were revealed, and the selective effect of additives on specific crystal faces was evaluated. It is anticipated that this work may provide a facile approach for the fabrication of one-dimensional functional materials.
منابع مشابه
Self-assembling 1D core/shell microrods by the introduction of additives: a one-pot and shell-tunable method† †Electronic supplementary information (ESI) available: SEM images of Mela-DM·HCl; confocal fluorescence microscopy image and fluorescence spectrum of Mela-DM/Mela-M-Pym·HCl microrods; SEM and fluorescence microscopy images of Mela-M-Pym·HCl; SEM image of Mela-DM/Mela-M-Pym·HCl microrods prepared at –20 °C; SEM images of Mela-DM/Mela-M-R·HCl microrods; fluorescence microscopy and SEM images of Mela-DM/Mela-M-Pym·HCl after exposure to ammonia; experimental details and compound characterization; details of the single crystal structure of Mela-DM·HCl. CCDC 1063152. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01631b Click here for additional data file. Click here for additional data file.
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ورودعنوان ژورنال:
- Chemical science
دوره 6 8 شماره
صفحات -
تاریخ انتشار 2015